Radiation curable composition including an acrylated...

G - Physics – 03 – C

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96/191, 96/204,

G03C 11/08 (2006.01) C08F 299/06 (2006.01) G03C 11/06 (2006.01) G03F 7/075 (2006.01)

Patent

CA 1172790

- ii - RADIATION CURABLE COMPOSITION FOR RESTORATIVE AND/OR PROTECTIVE TREATMENT OF PHOTOGRAPHIC ELEMENTS ABSTRACT OF THE DISCLOSURE Radiation curable compositions useful for restorative and/or protective treatment of photo- graphic elements are comprised of an acrylated urethane, an aliphatic ethylenically-unsaturated carboxylic acid, a multifunctional acrylate, and a siloxy-containing polycarbinol. Photographic elements, such as still films, motion picture films, paper prints, microfiche, and the like, are provided with a protective overcoat layer which is permanently bonded to the element, and serves to protect it from abrasion and scratches, by coating the element with the radiation-curable composition and irradiating the coating to bond it to the element and cure it to form a transparent, flexible, scratch-resistant, cross- linked polymeric layer. The protective overcoat layer can be applied to the image-bearing side of the element or to the support side of the element or to both sides. The radiation-curable composition can also be used as a restorative composition in the treat- ment of photographic elements which have scratches, abrasion marks, and the like, which impair the appearance or projection capabilities of the element. In use as a restorative composition, the radiation- curable composition can be applied locally in the region of the defects only, to effectively eliminate them and restore the element to a substantially defect-free condition, or it can be applied over the entire surface of the element to both eliminate the defects and form a protective overcoat layer that is capable of providing protection against subsequent scratching or abrasion.

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