Substituted benzoyl ketones, methods for producing them and...

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 233/32 (2006.01) A01N 43/50 (2006.01) A01N 43/54 (2006.01) A01N 43/653 (2006.01) C07D 209/48 (2006.01) C07D 213/64 (2006.01) C07D 231/20 (2006.01) C07D 233/42 (2006.01) C07D 233/70 (2006.01) C07D 237/32 (2006.01) C07D 239/10 (2006.01) C07D 249/08 (2006.01) C07D 249/12 (2006.01) C07D 249/14 (2006.01) C07D 253/04 (2006.01) C07D 263/58 (2006.01) C07D 275/06 (2006.01) C07D 285/13 (2006.01) C07D 471/04 (2006.01) C07D 487/04 (2006.01)

Patent

CA 2373076

The invention relates to novel substituted benzoyl ketones of formula (I), wherein n represents 0, 1, 2 or 3; A represents a simple bond or alkanediyl (alkylene); R1 represents hydrogen or optionally substituted alkyl or cycloalkyl; R2 represents hydrogen, cyano, carbamoyl, halogen, or optionally substituted alkyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulfinyl or alkylsulfonyl; R3 represents hydrogen, nitro, cyano, carboxy, carbamoyl, thiocarbamoyl, halogen or optionally substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino or dialkylaminosulfonyl; R4 represents nitro, cyano, carboxy, carbamoyl, thiocarbamoyl, halogen or optionally substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino or dialkylaminosulfonyl; and Z represents an optionally substituted 4 to 12- membered, saturated or unsaturated, monocyclic or bicyclic, heterocyclic grouping containing 1 to 4 hetero atoms (up to 4 nitrogen atoms and optionally, - alternatively or additionally - an oxygen atom or a sulphur atom, or an SO2 grouping), which also contains one to three oxo-groups (C=O) and/or thioxo-groups (C=S) as constituents of the heterocycle. The invention also relates to methods for producing the inventive substituted benzoyl ketones and to their use as herbicides.

Cette invention concerne des cétones de benzoyle substituées de formule (I), dans laquelle: n vaut 0, 1, 2, ou 3; A est une liaison simple ou alcandiyle (alkylène); R?1¿ est hydrogène, ou alkyle ou cycloalkyle éventuellement substitué; R?2¿ est hydrogène, cyano, carbamoyle, halogène, ou alkyle, alkoxy, alkoxycarbonyle, alkylthio, alkylsulfinyle ou alkylsulfonyle éventuellement substitué; R?3¿ est hydrogène, nitro, cyano, carboxy, carbamoyle, thiocarbamoyle, halogène, ou alkyle, alkoxy, alkylthio, alkylsulfinyle, alkylsulfonyle, alkylamino, dialkylamino ou dialkylaminosulfonyle éventuellement substitué; R?4¿ est nitro, cyano, carboxy, carbamoyle, thiocarbamoyle, halogène, ou alkyle, alkoxy, alkylthio, alkylsulfinyle, alkylsulfonyle, alkylamino, dialkylamino ou dialkylaminosulfonyle éventuellement substitué; et Z est un groupe hétérocyclique, monocyclique ou bicyclique, saturé ou non, possédant 4 à 12 éléments, comprenant 1 à 4 hétéroatomes (jusqu'à 4 atomes d'azote et éventuellement - de manière alternative ou en supplément- un atome d'oxygène ou un atome de soufre, ou un groupe SO ou un groupe SO¿2?, et contenant en plus un à trois groupes oxo (C=O) et/ou groupes thioxo (C=S) comme éléments de l'hétérocycle. L'invention concerne également un procédé de préparation ces composés et leur utilisation de comme herbicides.

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