Substituted indenyl containing metal complexes and olefin...

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 17/00 (2006.01) C08F 4/64 (2006.01) C08F 10/00 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2229608

Group 4 metal complexes comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, catalytic derivatives thereof and their use as olefin polymerization catalysts are disclosed.

L'invention porte sur des complexes de métaux du groupe IV contenant un groupe indényle substitué en position 2 et 3 par au moins un groupe choisi parmi hydrocarbyle, hydrocarbyle à substitution perfluoro, silyle, germyle ou leurs mélanges, ledit groupe indényle étant de plus lié par covalence au métal par un groupe ligand bivalent ou ses dérivés catalytiques. L'invention porte également sur leur utilisation comme catalyseurs de polymérisation des oléfines.

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