Telomers

Details Telomers Telomers

C - Chemistry, Metallurgy

07

F

C07F 9/38 (2006.01) C02F 5/00 (2006.01) C02F 5/14 (2006.01) C07F 9/30 (2006.01) C07F 9/655 (2006.01) C08F 2/38 (2006.01) C08F 8/40 (2006.01) C08G 79/04 (2006.01) C09K 15/32 (2006.01) C23F 11/10 (2006.01) C23F 11/173 (2006.01)

Patent

CA 2070091

Abstract of the Disclosure Telomers An aqueous process for the production of a (co)telomer having the formula I: Image I in which X5 is hydrogen, C1-C4 alkyl, phenyl, an alkali metal - or alkaline earth metal atom, or an ammonium or amine residue; A2 is a homopolymer residue having the formula II: Image IV or A2 is a copolymer residue comprising two or more different residues -[CH(W1)-C(W2)(W3)]-r in which W1 is hydrogen, methyl or a residue -CO2W4 in which W4 is hydrogen or C1-C8 alkyl, optionally substituted by a hydroxy group, W2 is hydrogen, C1-C4 alkyl, hydroxymethyl, -CO2W5 in which W5 is hydrogen, a residue of formula: a residue of formula: Image in which W6 is hydrogen, methyl or phenyl and s is an integer ranging from 1 to 100, or W5 is C1-8 alkyl which is optionally substituted by SO3X5 in which X5 has its previous significance; W3 is a residue - CO2W4 in which W4 has its previous significance, or W3 is C1-8alkyl optionally substituted by one or two carboxylic acid groups, or is a phenyl residue optionally substituted by hydroxyl or SO3X5 in which X5 has its previous significance, or W3 is acetyl, hydroxymethyl, hydroxyl, acetomethyl, SO3X5. CH2SO3X5 or (X5)2 in which X5 has its previous significance, a residue CONW7W8 in which W7 and W8 are the same or different and each is hydrogen, C1-8 alkyl, hydroxymethyl or a residue CH(OH)CO2X5, C(CH3)2CH2SO3X5, C(CH3)2CH2CO2X5 or C(CH3)2CH2PO3(X5)2 in which X5 has its previous significance, or N(W9)COCH3 in which W9 is hydrogen or C1-4 alkyl, or W3 is -CH2[O(CH2)p]sOW9 in which W9 and s have their previous significance and p is an integer from 1 to 12 or W3 and W1 may form a carboxylic acid anhydride moiety -CO.O.CO-; and r is an integer ranging from 2 to 100, which process comprises reacting, in an aqueous medium, a compound having the formula III: Image III in which X5 has its previous significance, Y is OR3 in which R3 is hydrogen or C1-4 alkyl or NR4R5 in which R4 and R5, independently, are hydrogen or C1-4 alkyl, or R4 and R5, together with the nitrogen atom to which they are attached, can form an N-heterocyclic ring; and R1 and R2, independently, are hydrogen or C1-4 alkyl or R1 and R2, together with the carbon atom to which they are attached, may form a cyclopentyl or cyclohexyl ring, with r moles of an olefin of formula IV: CH(W1) = C(W2)(W3) IV in which W1, W2 and W3 have their previous significance, to form a compound having the formula V: Image V in which Y, R1, R2, X5 and A2 have their previous significance; and then converting the compound of formula V to a compound of formula I. The compounds of formula V are new compounds.

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