Thermal process for the conversion of uranium hexafluoride

C - Chemistry – Metallurgy – 01 – G

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C01G 43/025 (2006.01) C01B 7/19 (2006.01)

Patent

CA 2264613

A single-step process for producing solid uranium oxide and gaseous HF from UF6 which comprises bringing together two gaseous reactant streams, one of said streams comprising UF6 optionally admixed with oxygen as O2, and the second reactant stream comprising a mixture of hydrogen as H2 or as a hydrogen- containing compound and oxygen as an oxygen-containing compound, said gaseous reactant streams being brought together at a temperature and composition such that the UF6 is converted rapidly by flame reaction into readily separable solid uranium oxide and a gaseous HF product.

Un procédé de production, en une étape, d'oxyde d'uranium solide et de fluorure d'hydrogène à partir d'hexafluorure d'uranium UF6 consiste à mettre ensemble deux flux de réactifs gazeux, un desdits flux comprenant UF6 éventuellement mélangé à de l'oxygène sous forme de O2, le second flux du réactif comprenant un mélange d'hydrogène sous forme de H2 ou d'un composé contenant de l'hydrogène et de l'oxygène sous forme d'un composé contenant de l'oxygène, lesdits flux de réactifs gazeux étant mis ensemble à une température et en une composition telles que l'UF6 est convertit rapidement par une réaction à la flamme en un oxyde d'uranium solide facilement séparable et un produit d'hexafluorure d'uranium gazeux.

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