Producing oximinosilanes, oximinogermanes and oximinostannanes

C - Chemistry – Metallurgy – 07 – F

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260/434, 260/446

C07F 7/10 (2006.01) C07F 7/08 (2006.01) C07F 7/22 (2006.01) C07F 7/30 (2006.01)

Patent

CA 1192908

ABSTRACT OF THE DISCLOSURE A Group IVa metal halide such as methyl tri- chlorosilane is reacted with an oxime compound such as methyl ethyl ketone oxime in the absence of a base to form in high yields a product oximinosilane, oximinoger- mane or oximinostannane (e.g. methyl tris(methyl ethyl ketoximo)silane) and a by-product oxime hydrohalide. The oxime above that is found in the product may be recovered by neutralization of the by-product oxime hydrohalide. The products can be useful in a variety of applications, and especially as room temperature vulcanizing or curing agents for silicones.

416468

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